By E.I. Altman, M. Bienfait, H.P. Bonzel, R. Diehl, M.Y.L. Jung, V.G. Lifshitz, M.E. Michel, R. Miranda, R. McGrath, K. Oura, A.A. Saranin, E.G. Seebauer, P. Zeppenfeld, A.V. Zotov

ISBN-10: 3540412239

ISBN-13: 9783540412236

Floor technological know-how is known as a comparatively younger clinical self-discipline, keen on the actual and chemical homes of and phenomena on fresh and coated sturdy surfaces, studied less than quite a few stipulations. The adsorption of atoms and molecules on good surfaces is, for instance, any such situation, hooked up with kind of drastic alterations of all floor homes. An adsorption occasion is often saw in nature and located to be of technical significance in lots of business approaches. consequently, floor technology is interdisciplinary through its very nature, and as such a tremendous middleman among basic and utilized study. the current quantity forty two is dedicated to coated stable Surfaces and, particularly, Subvolume A to Adsorbed Layers on Surfaces. it really is as the sort of number of facts bought for adsorbates on well-defined crystalline surfaces. "Well-defined" potential surfaces of recognized crystallographic constitution and chemical composition.

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Extra info for Adsorption on Surfaces and Surface Diffusion of Adsorbates (Landolt-Börnstein: Numerical Data and Functional Relationships in Science and Technology - New Series Condensed Matter)

Example text

Another complication in comparing data from different techniques may arise from the possibility that several surface diffusion mechanisms may be operative. Evidence for different surface diffusion mechanisms may be revealed by large differences in measured activation energies and by large differences in absolute values of measured surface diffusion coefficients at the same temperature. Hence experimental data, especially if they originate from different techniques, need to be be compared systematically in order to decide whether the effective rates of diffusion (at the same or at different temperatures) may be indicative of different diffusion mechanisms.

This coverage was achieved at room temperature by maintaining a background pressure of CO of 1×10–6 mbar in the vacuum chamber (compare the isotherm in Fig. 11). Figure 19 shows two images of the (2×1)p2mg-CO layer, taken at two different bias voltages. The (2×1) unit cell is indicated and it can be clearly seen that there are two CO molecules per unit cell. The CO molecules show a zig-zag arrangement along the [1 1 0] glide direction and a mirror plane perpendicular to it. These are exactly the characteristic features of the (2×1)p2mg unit cell.

Under special assumptions, values of 106 kJ/mol and 15 kJ/mol are separately obtained for the heat of adsorption and the CO–CO interaction energy, respectively. These energies are not coverage-specific. Because of the separation of the heat of adsorption into an energy of adsorption of an isolated CO and the energy of lateral CO interaction, the value of 106 kJ/mol should be compared to the heat of adsorption at zero coverage in Fig. 10. 3 Orientation of adsorbed molecules With regard to the structure of an adsorbed molecule or radical on a crystalline metal or semiconductor surface, answers on different levels of complexity can be sought.

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Adsorption on Surfaces and Surface Diffusion of Adsorbates (Landolt-Börnstein: Numerical Data and Functional Relationships in Science and Technology - New Series Condensed Matter) by E.I. Altman, M. Bienfait, H.P. Bonzel, R. Diehl, M.Y.L. Jung, V.G. Lifshitz, M.E. Michel, R. Miranda, R. McGrath, K. Oura, A.A. Saranin, E.G. Seebauer, P. Zeppenfeld, A.V. Zotov


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